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2054_SF

1-Ethyl-3-methyl-imidazolium-ethylsulphate (EMIM EtOSO3), 100 g
≥98 %
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EMIM EtOSO3
Empirical formula C8H16N2O4S
Molar mass (M) 236,29 g/mol
Density (D) 1,239 g/cm³
Boiling point (bp) >140 °C
Flash point (flp) 176 °C
Melting point (mp) -53 °C
WGK 1
CAS No. [342573-75-5]

Ionic liquid

Type analysis

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Art. No. 2054.2

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1-Ethyl-3-methyl-imidazolium-ethylsulphate (EMIM EtOSO3) ≥98 %

Technical Information
Alternative Name EMIM EtOSO3 
1-Ethyl-3-methyl-imidazolium-ethylsulphate (EMIM EtOSO3)
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General information

Ionic Liquids

Ionic liquids are salts which are available in a liquid state over a wide temperature range. They constitute a new generation of solvents with considerable potential for being able to replace classic organic solvents. Ionic liquids are composed of organic cations and organic or inorganic anions. Due to their fully ionized composition they exhibit no vapor pressure over the entire liquid range.

• Low-melting with melting point under 100 °C
• Thermally, mechanically and electrochemically stable
• Neither volatile nor combustible
• Negligible vapor pressure
• High solubility of many different kinds of chemicals


Chemical and physical properties of ionic liquids:

Art. No. Ionic liquid Short name Density Melting point (°C) Viscosity (cP) Conductivity (mS/cm) Thermal stability / pyrolysis
2010 1-Butyl-3-methyl-imidazolium-chloride BMIM Cl n. e. 65 n. e. n. e. approx. 200 °C*
2012 1-Butyl-3-methyl-imidazolium-hexafluorophosphate BMIM PF6 1,372 (23 °C) -8 267,1 (25 °C) 1,373 (20 °C) approx. 200 °C, with water hydrolysis under HF formation*
2014 1-Butyl-3-methyl-imidazolium-tetrafluoroborate BMIM BF4 1,205 (22 °C) -75 103,5 (25 °C) 3,145 (20 °C) approx. 200 °C, with water hydrolysis under HF formation*
2015 1-Butyl-3-methyl-imidazolium-trifluoromethanesulphonate BMIM OTf 1,299 (24 °C) 16 80 (25 °C) 3,049 (20 °C) <250 °C*
2021 1-Butyl-1-methyl-pyrrolidinium-bis-(trifluoromethylsulphonyl)-imide BMPyrr BTA 1,395 (23 °C) -18 94,4 (20 °C) 2,12 (20 °C) <250 °C*
2022 1-Butyl-1-methyl-pyrrolidinium-dicyanamide BMPyrr DCA 1,023 (20 °C) -55 46,4 (20 °C) 10,83 (30 °C) <80 °C / >80 °C discolouration*
2025 Butyl-trimethyl-ammonium-bis-(trifluoromethylsulphonyl)-imide N1114 BTA 1,395 (24 °C) 7 106 (21 °C) 2,861 (30 °C) <250 °C*
2028 Choline-dihydrogenphosphate Choline DHP n. e. 190 n. e. n. e. n. e.
2035 Ethylammonium-nitrate EAN 1,209 (26 °C) 9 36,5 (25 °C) 25,36 (30 °C) n. e.
2037 1-Ethyl-3-methyl-imidazolium-bromide EMIM Br n. e. 91 n. e. n. e. approx. 200 °C*
2053 1-Ethyl-3-methyl-imidazolium-dicyanamide EMIM DCA 1,101 (26 °C) -21 16,8 (21 °C) 25,3 (21 °C) <80 °C / >80 °C discolouration*
2054 1-Ethyl-3-methyl-imidazolium-ethylsulphate EMIM EtSO4 1,241 (24 °C) n. e. 94,2 (25 °C) 5,560 (30 °C) n. e.
2056 1-Ethyl-3-methyl-imidazolium-methanesulphonate EMIM OMs 1,242 (23 °C) n. e. 134,5 (25 °C) 3,693 (30 °C) <250 °C*
2059 1-Ethyl-3-methyl-imidazolium-thiocyanate EMIM SCN 1,119 (25 °C) -6 24,7 (20 °C) 17,87 (20 °C) <80 °C / >80 °C discolouration*
2062 1-Ethyl-3-methyl-imidazolium-trifluoromethansulphonate EMIM OTf 1,386 (25 °C) -9 39,8 (25 °C) 9,842 (30 °C) <250 °C*
2064 1-Hexyl-3-methyl-imidazolium chloride HMIM Cl 1,041 (26 °C) -75 3302 (35 °C) 0,076 (30 °C) <200 °C*
2069 1-Hexyl-3-methyl-imidazolium-hexafluorophosphate HMIM PF6 1,298 (23 °C) -61 464,7 (25 °C) 0,076 (30 °C) <200 °C, with water hydrolysis under HF formation*
2070 1-Hexyl-3-methyl-imidazolium-tetrafluoroborate HMIM BF4 1,148 (24 °C) -82 288,3 (20 °C) 1,176 (20 °C) <200 °C, with water hydrolysis under HF formation*
2076 1-Methyl-3-octyl-imidazolium-hexafluorophosphate OMIM PF6 1,237 (24 °C) -70 608,3 (25 °C) 0,444 (30 °C) <200 °C, with water hydrolysis under HF formation*
2081 1-Methyl-3-octyl-imidazolium-tetrafluoroborate OMIM BF4 1,106 (19 °C) -81 760,3 (20 °C) 1,266 (30 °C) <200 °C, with water hydrolysis under HF formation*
2091 1-Methyl-3-propyl-imidazolium-iodide PMIM I 1,542 (24 °C) n. e. 1385 (20 °C) 0,958 (30 °C) n. e.
2095 1-Methyl-1-propyl-piperidinium-bis-(trifluoromethylsulphonyl)- imide PMPip BTA 1,413 (23 °C) 9 175,5 (25 °C) 2,124 (30 °C) approx. 250 °C*
2096 Triethylsulfonium-bis-(trifluoromethylsulphonyl)-imide S222 BTA 1,462 (24 °C) n. e. 38,9 (20 °C) 5,12 (25 °C) n. e.
*Experience values, not guaranteed / n.e. = not evaluated

Solubility of ionic liquids:

Art. No. Ionic liquid Short name Water Isopropanol Acetone Acetonitrile Toluene Heptane
2010 1-Butyl-3-methyl-imidazolium-chloride BMIM Cl Y Y Y Y N N
2012 1-Butyl-3-methyl-imidazolium-hexafluorophosphate BMIM PF6 N N Y Y N N
2014 1-Butyl-3-methyl-imidazolium-tetrafluoroborate BMIM BF4 Y N Y Y N N
2015 1-Butyl-3-methyl-imidazolium-trifluoromethanesulphonate BMIM OTf Y Y Y Y N N
2021 1-Butyl-1-methyl-pyrrolidinium-bis-(trifluoromethylsulphonyl)-imide BMPyrr BTA N Y Y Y N N
2022 1-Butyl-1-methyl-pyrrolidinium-dicyanamide BMPyrr DCA Y Y Y Y N N
2025 Butyl-trimethyl-ammonium-bis-(trifluoromethylsulphonyl)-imide N1114 BTA N Y Y Y N N
2028 Choline-dihydrogenphosphate Choline DHP Y N N N N N
2035 Ethylammonium-nitrate EAN Y Y Y Y N N
2037 1-Ethyl-3-methyl-imidazolium-bromide EMIM Br Y Y N Y N N
2053 1-Ethyl-3-methyl-imidazolium-dicyanamide EMIM DCA Y Y Y Y N N
2054 1-Ethyl-3-methyl-imidazolium-ethylsulphate EMIM EtSO4 Y Y Y Y N N
2056 1-Ethyl-3-methyl-imidazolium-methanesulphonate EMIM OMs Y Y Y Y Y N
2059 1-Ethyl-3-methyl-imidazolium-thiocyanate EMIM SCN Y Y Y Y N N
2062 1-Ethyl-3-methyl-imidazolium-trifluoromethansulphonate EMIM OTf Y Y Y Y T N
2064 1-Hexyl-3-methyl-imidazolium chloride HMIM Cl Y Y Y Y N N
2069 1-Hexyl-3-methyl-imidazolium-hexafluorophosphate HMIM PF6 N N Y Y N N
2070 1-Hexyl-3-methyl-imidazolium-tetrafluoroborate HMIM BF4 N Y Y Y N N
2076 1-Methyl-3-octyl-imidazolium-hexafluorophosphate OMIM PF6 N N Y Y Y N
2081 1-Methyl-3-octyl-imidazolium-tetrafluoroborate OMIM BF4 N Y Y Y N N
2091 1-Methyl-3-propyl-imidazolium-iodide PMIM I Y Y Y Y N N
2095 1-Methyl-1-propyl-piperidinium-bis-(trifluoromethylsulphonyl)- imide PMPip BTA N Y Y Y T N
2096 Triethylsulfonium-bis-(trifluoromethylsulphonyl)-imide S222 BTA N N Y Y N N
Y = miscibel / N = non miscibel / T = partially miscibel

Certificates of Analysis

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The following analysis certificates have been found:

Type analysis

Appearanceyellow to orange liquid  
Assay≥98 %  
Water (KF)≤0,05 %  

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