Jump to content Jump to navigation menu

Technical Data Sheet
SPECIAL OFFER
20N7_SF

1-Ethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide (EMIM TFSI), 50 g
From  proionic
≥99,9 %, Electronic Grade
Icon_ROTH-for-Future_Bronze Products with optimised manufacturing process in terms of sustainability. You can find more information here.
Icon_EVE-EUD Please consider that this product might be liable to some legal sanctions as for example to obtain an end user declaration or the prohibition of some applications. For details please do contact your counterpart in our sales department!
Examples of effect: In smaller quantities, lead to immediate serious damage to health or death. Safety: Do not inhale, touch or swallow. Wear work safety equipment. Call a poison control centre or doctor immediately. Recovery position.
Danger
H301-H412
i toxic if swallowed, harmful to aquatic life with long lasting effects
P264 P270 P273 P301+P310 P330 P501
i wash thoroughly after handling, do not eat, drink or smoke when using this product, avoid release to the environment, IF SWALLOWED: Immediately call a POISON CENTER/doctor, rinse mouth, dispose of contents/container to industrial combustion plant
Pack Qty.
Pack.
EMIM BTA, EMIM TFSI, EMIM NTf2
Empirical formula C8H11F6N3O4S2
Molar mass (M) 391.31 g/mol
Density (D) 1,525 g/cm³
Flash point (flp) 337,5 °C
Melting point (mp) -16 °C
ADR 6.1 III
WGK 2
CAS No. 174899-82-2
EG-Nr. 700-235-5
UN-Nr. 2810


€209.65 /Pack Qty.

€167.70/Pack Qty.  Campaign price!

excl. VAT. | 50 g per Pack Qty.

Art. No. 20N7.2

In stock
Delivery fast, simple and reliable!
Free of shipping costs from 250 €

Product details



1-Ethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide (EMIM TFSI) ≥99,9 %, Electronic Grade

Technical Information
Storage under inert gas recommended 
ROTH for Future Score - sustainability criteria • Product features 
• Transport 
You can find further information on our website - Sustainability criteria at Carl ROTH. 
1-Ethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide (EMIM TFSI)
Selected quantity:   0
  1. Subtotal:  0.00
Art. No. Pack Qty. Pack. Price Quantity
20N7.1 10 g glass
€101.60

€81.25

20N7.2 50 g glass
€209.65

€167.70

In stock
Available (note delivery time)
In procurement
No longer available
Delivery date currently unknown
Selected quantity:   0
  1. Subtotal:  0.00

Downloads / MSDS

Specification / German

Specification / English

Specification / French
Security datasheet
Austria / German
Security datasheet
Germany / German
Security datasheet
International / English

General information

Ionic Liquids

Ionic liquids are salts which are available in a liquid state over a wide temperature range. Ionic liquids are composed of organic cations and organic or inorganic anions. Due to their fully ionic structure, they display a variety of interesting properties.

  • Negligible vapor pressure
  • Excellent chemical and thermal stability
  • Low-melting with melting point under 100 °C
  • High solubility to a wide range of substances and biopolymers
  • Uncomplicated and safe handling compared to conventional solvents
  • More environmentally friendly alternative to volatile, ecologically problematic organic solvents


Chemical and physical properties of ionic liquids:

Art. No. Ionic liquid Short name Density Melting point (°C) Viscosity (cP) Conductivity (mS/cm) Thermal stability / pyrolysis
2010 1-Butyl-3-methyl-imidazolium-chloride BMIM Cl n. e. 65 n. e. n. e. approx. 200 °C*
2012 1-Butyl-3-methyl-imidazolium-hexafluorophosphate BMIM PF6 1,372 (23 °C) -8 267,1 (25 °C) 1,373 (20 °C) approx. 200 °C, with water hydrolysis under HF formation*
2014 1-Butyl-3-methyl-imidazolium-tetrafluoroborate BMIM BF4 1,205 (22 °C) -75 103,5 (25 °C) 3,145 (20 °C) approx. 200 °C, with water hydrolysis under HF formation*
2015 1-Butyl-3-methyl-imidazolium-trifluoromethanesulphonate BMIM OTf 1,299 (24 °C) 16 80 (25 °C) 3,049 (20 °C) <250 °C*
2021 1-Butyl-1-methyl-pyrrolidinium-bis-(trifluoromethylsulphonyl)-imide BMPyrr BTA 1,395 (23 °C) -18 94,4 (20 °C) 2,12 (20 °C) <250 °C*
2022 1-Butyl-1-methyl-pyrrolidinium-dicyanamide BMPyrr DCA 1,023 (20 °C) -55 46,4 (20 °C) 10,83 (30 °C) <80 °C / >80 °C discolouration*
2025 Butyl-trimethyl-ammonium-bis-(trifluoromethylsulphonyl)-imide N1114 BTA 1,395 (24 °C) 7 106 (21 °C) 2,861 (30 °C) <250 °C*
2028 Choline-dihydrogenphosphate Choline DHP n. e. 190 n. e. n. e. n. e.
2035 Ethylammonium-nitrate EAN 1,209 (26 °C) 9 36,5 (25 °C) 25,36 (30 °C) n. e.
2037 1-Ethyl-3-methyl-imidazolium-bromide EMIM Br n. e. 91 n. e. n. e. approx. 200 °C*
2053 1-Ethyl-3-methyl-imidazolium-dicyanamide EMIM DCA 1,101 (26 °C) -21 16,8 (21 °C) 25,3 (21 °C) <80 °C / >80 °C discolouration*
2054 1-Ethyl-3-methyl-imidazolium-ethylsulphate EMIM EtSO4 1,241 (24 °C) n. e. 94,2 (25 °C) 5,560 (30 °C) n. e.
2056 1-Ethyl-3-methyl-imidazolium-methanesulphonate EMIM OMs 1,242 (23 °C) n. e. 134,5 (25 °C) 3,693 (30 °C) <250 °C*
2059 1-Ethyl-3-methyl-imidazolium-thiocyanate EMIM SCN 1,119 (25 °C) -6 24,7 (20 °C) 17,87 (20 °C) <80 °C / >80 °C discolouration*
2062 1-Ethyl-3-methyl-imidazolium-trifluoromethansulphonate EMIM OTf 1,386 (25 °C) -9 39,8 (25 °C) 9,842 (30 °C) <250 °C*
2064 1-Hexyl-3-methyl-imidazolium chloride HMIM Cl 1,041 (26 °C) -75 3302 (35 °C) 0,076 (30 °C) <200 °C*
2069 1-Hexyl-3-methyl-imidazolium-hexafluorophosphate HMIM PF6 1,298 (23 °C) -61 464,7 (25 °C) 0,076 (30 °C) <200 °C, with water hydrolysis under HF formation*
2070 1-Hexyl-3-methyl-imidazolium-tetrafluoroborate HMIM BF4 1,148 (24 °C) -82 288,3 (20 °C) 1,176 (20 °C) <200 °C, with water hydrolysis under HF formation*
2076 1-Methyl-3-octyl-imidazolium-hexafluorophosphate OMIM PF6 1,237 (24 °C) -70 608,3 (25 °C) 0,444 (30 °C) <200 °C, with water hydrolysis under HF formation*
2081 1-Methyl-3-octyl-imidazolium-tetrafluoroborate OMIM BF4 1,106 (19 °C) -81 760,3 (20 °C) 1,266 (30 °C) <200 °C, with water hydrolysis under HF formation*
2091 1-Methyl-3-propyl-imidazolium-iodide PMIM I 1,542 (24 °C) n. e. 1385 (20 °C) 0,958 (30 °C) n. e.
2095 1-Methyl-1-propyl-piperidinium-bis-(trifluoromethylsulphonyl)- imide PMPip BTA 1,413 (23 °C) 9 175,5 (25 °C) 2,124 (30 °C) approx. 250 °C*
2096 Triethylsulfonium-bis-(trifluoromethylsulphonyl)-imide S222 BTA 1,462 (24 °C) n. e. 38,9 (20 °C) 5,12 (25 °C) n. e.
*Experience values, not guaranteed / n.e. = not evaluated

Solubility of ionic liquids:

Art. No. Ionic liquid Short name Water Isopropanol Acetone Acetonitrile Toluene Heptane
2010 1-Butyl-3-methyl-imidazolium-chloride BMIM Cl Y Y Y Y N N
2012 1-Butyl-3-methyl-imidazolium-hexafluorophosphate BMIM PF6 N N Y Y N N
2014 1-Butyl-3-methyl-imidazolium-tetrafluoroborate BMIM BF4 Y N Y Y N N
2015 1-Butyl-3-methyl-imidazolium-trifluoromethanesulphonate BMIM OTf Y Y Y Y N N
2021 1-Butyl-1-methyl-pyrrolidinium-bis-(trifluoromethylsulphonyl)-imide BMPyrr BTA N Y Y Y N N
2022 1-Butyl-1-methyl-pyrrolidinium-dicyanamide BMPyrr DCA Y Y Y Y N N
2025 Butyl-trimethyl-ammonium-bis-(trifluoromethylsulphonyl)-imide N1114 BTA N Y Y Y N N
2028 Choline-dihydrogenphosphate Choline DHP Y N N N N N
2035 Ethylammonium-nitrate EAN Y Y Y Y N N
2037 1-Ethyl-3-methyl-imidazolium-bromide EMIM Br Y Y N Y N N
2053 1-Ethyl-3-methyl-imidazolium-dicyanamide EMIM DCA Y Y Y Y N N
2054 1-Ethyl-3-methyl-imidazolium-ethylsulphate EMIM EtSO4 Y Y Y Y N N
2056 1-Ethyl-3-methyl-imidazolium-methanesulphonate EMIM OMs Y Y Y Y Y N
2059 1-Ethyl-3-methyl-imidazolium-thiocyanate EMIM SCN Y Y Y Y N N
2062 1-Ethyl-3-methyl-imidazolium-trifluoromethansulphonate EMIM OTf Y Y Y Y T N
2064 1-Hexyl-3-methyl-imidazolium chloride HMIM Cl Y Y Y Y N N
2069 1-Hexyl-3-methyl-imidazolium-hexafluorophosphate HMIM PF6 N N Y Y N N
2070 1-Hexyl-3-methyl-imidazolium-tetrafluoroborate HMIM BF4 N Y Y Y N N
2076 1-Methyl-3-octyl-imidazolium-hexafluorophosphate OMIM PF6 N N Y Y Y N
2081 1-Methyl-3-octyl-imidazolium-tetrafluoroborate OMIM BF4 N Y Y Y N N
2091 1-Methyl-3-propyl-imidazolium-iodide PMIM I Y Y Y Y N N
2095 1-Methyl-1-propyl-piperidinium-bis-(trifluoromethylsulphonyl)- imide PMPip BTA N Y Y Y T N
2096 Triethylsulfonium-bis-(trifluoromethylsulphonyl)-imide S222 BTA N N Y Y N N
Y = miscibel / N = non miscibel / T = partially miscibel

Certificates of Analysis

You can search for and download your certificate of analysis for the selected product here. Please provide your batch number.
The following analysis certificates have been found:

Type analysis

Appearanceclear liquid
Colour (APHA)≤250
Halogens≤0,001 %
Water content (KF)≤0,002 %
Assay (1-alkylimidazole)≤0.05 %
ΔE> 4,5 V, WE: Pt, CE: Pt, RE: W/WO3; 10mV/s ± 1 mA/cm2